Issue 9, 2017
From the journal:

Organic Chemistry Frontiers

Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters†

Hong Fu,a   Tao Yang,a   Jia-Qi Shang,a   Jia-Li Zhou,a   Meng Sun ORCID logo b  and  Ya-Min Li ORCID logo *a  

* Corresponding authors

a Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming 650500, P. R. China
E-mail: liym@kmust.edu.cn

b Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi'an 710127, P. R. China

Abstract

A copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates is developed. This transformation exhibits a wide substrate scope and good functional group tolerance, providing a straightforward and highly efficient access to acyl phosphate esters. A possible mechanism for the reaction is proposed.

Graphical abstract: Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters

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Article information

DOI
https://doi.org/10.1039/C7QO00298J
Article type
Research Article
Submitted
18 Apr 2017
Accepted
02 Jun 2017
First published
05 Jun 2017

Org. Chem. Front., 2017,4, 1777-1780

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Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters

H. Fu, T. Yang, J. Shang, J. Zhou, M. Sun and Y. Li, Org. Chem. Front., 2017, 4, 1777 DOI: 10.1039/C7QO00298J

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