Issue 1, 2017

Chiral carbon–sulfur center formation via Pd-catalyzed asymmetric allylic thioetherification: synthesis of allylic thioethers

Abstract

Pd-catalyzed asymmetric allylic thioetherification reaction of various sodium thiolates was realized, which gave the allylic thioethers in good to high yields with high enantioselectivities. The reaction results considerably depend on the substrates and the bulky sulfur nucleophile led to excellent enantioselectivity as well.

Graphical abstract: Chiral carbon–sulfur center formation via Pd-catalyzed asymmetric allylic thioetherification: synthesis of allylic thioethers

Supplementary files

Article information

Article type
Communication
Submitted
16 Nov 2016
Accepted
01 Dec 2016
First published
23 Dec 2016
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 256-259

Chiral carbon–sulfur center formation via Pd-catalyzed asymmetric allylic thioetherification: synthesis of allylic thioethers

J. Cai, J. Cai, P. Zheng, X. Wang and X. Zhao, RSC Adv., 2017, 7, 256 DOI: 10.1039/C6RA26877C

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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