Issue 10, 2017, Issue in Progress
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RSC Advances

CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides†

Ying Fu, ORCID logo *a   Yuhu Su,a   Qin-shan Xu,a   Zhengyin Du,a   Yulai Hu, ORCID logo a   Ke-Hu Wanga  and  Danfeng Huanga  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, P. R. China
E-mail: fuying@iccas.ac.cn
Fax: +86-931-7971989
Tel: +86-931-7971533

Abstract

A CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides/PPh3 has been explored. This reaction proceeded smoothly through an alkyl/aryl radical (generated from organometallics) under mild conditions and produced the desired sulfide products in excellent yields.

Graphical abstract: CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides

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Article information

DOI
https://doi.org/10.1039/C6RA27201K
Article type
Paper
Submitted
23 Nov 2016
Accepted
07 Jan 2017
First published
18 Jan 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 6018-6022

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CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides

Y. Fu, Y. Su, Q. Xu, Z. Du, Y. Hu, K. Wang and D. Huang, RSC Adv., 2017, 7, 6018 DOI: 10.1039/C6RA27201K

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