Issue 62, 2017, Issue in Progress
From the journal:

RSC Advances

Free-radical initiated cascade methylation or trideuteromethylation of isocyanides with dimethyl sulfoxides†

Rui Zhang,‡a   Xiaoqian Shi,‡a   Qinqin Yan,a   Zejiang Li, ORCID logo *ab   Zheng Wang,a   Haifei Yu,a   Xiaoke Wang,a   Jing Qi ORCID logo *a  and  Menglu Jianga  

* Corresponding authors

a College of Chemistry & Environmental Science, Hebei University, Baoding, Hebei, P. R. China
E-mail: lizejiang898@126.com, qijinghbu2013@126.com

b Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, Baoding, Hebei, P. R. China

Abstract

The methylation or trideuteromethylation reaction of isocyanides with dimethyl sulfoxides in a radical way is developed, which offers a low-cost, easy-operation cascade methylation strategy for the synthesis of phenanthridines or isoquinolines.

Graphical abstract: Free-radical initiated cascade methylation or trideuteromethylation of isocyanides with dimethyl sulfoxides

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Article information

DOI
https://doi.org/10.1039/C7RA08484F
Article type
Paper
Submitted
01 Aug 2017
Accepted
03 Aug 2017
First published
08 Aug 2017
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2017,7, 38830-38833

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Free-radical initiated cascade methylation or trideuteromethylation of isocyanides with dimethyl sulfoxides

R. Zhang, X. Shi, Q. Yan, Z. Li, Z. Wang, H. Yu, X. Wang, J. Qi and M. Jiang, RSC Adv., 2017, 7, 38830 DOI: 10.1039/C7RA08484F

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