Issue 5, 2017

Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

Abstract

Carboxylation of aliphatic and benzyl diamines with electrochemically activated CO2 led to the synthesis of bis-O-alkyl carbamates in high yields. Reaction conditions, including the geometry of the electrochemical cell, were discussed and optimized. This resulted in a significant reduction of unwanted material associated with the reaction, overcoming the economic and environmental restrictions to its application on large scale.

Graphical abstract: Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

Supplementary files

Article information

Article type
Communication
Submitted
12 Jul 2017
Accepted
29 Aug 2017
First published
29 Aug 2017

React. Chem. Eng., 2017,2, 646-649

Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

G. Forte, I. Chiarotto, F. Richter, V. Trieu and M. Feroci, React. Chem. Eng., 2017, 2, 646 DOI: 10.1039/C7RE00101K

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