An unconventional cleavage of an unstrained carbon–carbon bond in allylic alcohols can be induced by the use of N-fluorobenzenesulfonimide (NFSI) under catalyst-free conditions. By using this simple procedure, a wide range of functionalized Z-fluoroalkenes can be accessed in high yield and selectivity from cyclic and acyclic allylic alcohols.
T. Liu, J. Wu and Y. Zhao, Chem. Sci., 2017, 8, 3885 DOI: 10.1039/C7SC00483D
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