Issue 34, 2017

Neutron reflectometry yields distance-dependent structures of nanometric polymer brushes interacting across water

Abstract

The interaction between surfaces displaying end-grafted hydrophilic polymer brushes plays important roles in biology and in many wet-technological applications. In this context, the conformation of the brushes upon their mutual approach is crucial, because it affects interaction forces and the brushes' shear-tribological properties. While this aspect has been addressed by theory, experimental data on polymer conformations under confinement are difficult to obtain. Here, we study interacting planar brushes of hydrophilic polymers with defined length and grafting density. Via ellipsometry and neutron reflectometry we obtain pressure–distance curves and determine distance-dependent polymer conformations in terms of brush compression and reciprocative interpenetration. While the pressure–distance curves are satisfactorily described by the Alexander-de-Gennes model, the pronounced brush interpenetration as seen by neutron reflectometry motivates detailed simulation-based studies capable of treating brush interpenetration on a quantitative level.

Graphical abstract: Neutron reflectometry yields distance-dependent structures of nanometric polymer brushes interacting across water

Supplementary files

Article information

Article type
Paper
Submitted
29 May 2017
Accepted
20 Jul 2017
First published
24 Jul 2017
This article is Open Access
Creative Commons BY license

Soft Matter, 2017,13, 5767-5777

Neutron reflectometry yields distance-dependent structures of nanometric polymer brushes interacting across water

I. Rodriguez-Loureiro, E. Scoppola, L. Bertinetti, A. Barbetta, G. Fragneto and E. Schneck, Soft Matter, 2017, 13, 5767 DOI: 10.1039/C7SM01066D

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