Issue 6, 2018
From the journal:

Chemical Communications

Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit†

Lige Gong,a   Li Yu,b   Kai Yu, ORCID logo *a   Yong Ding, ORCID logo *b   Jinhua Lv,a   Chunmei Wang,a   Zhanhua Su ORCID logo a  and  Baibin Zhou ORCID logo *a  

* Corresponding authors

a Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin 150025, People's Republic of China
E-mail: hlyukai188@163.com, zhou_bai_bin@163.com

b State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University, Lanzhou 730000, People's Republic of China
E-mail: dingyong1@lzu.edu.cn

Abstract

A sandwich tungstobismuthate with new topology based on {B-β-BiW8O30}-cluster and unique 14-nuclear sandwich unit is reported as a high-efficiency visible light-driven water oxidation catalyst containing extended hetero-metal oxygen layer. At optimal conditions, the turn-over number (TON) of the title compound can reach 205.5 with O2 yield of 32.88%.

Graphical abstract: Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit

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Article information

DOI
https://doi.org/10.1039/C7CC06064E
Article type
Communication
Submitted
03 Aug 2017
Accepted
20 Dec 2017
First published
20 Dec 2017

Chem. Commun., 2018,54, 674-677

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Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit

L. Gong, L. Yu, K. Yu, Y. Ding, J. Lv, C. Wang, Z. Su and B. Zhou, Chem. Commun., 2018, 54, 674 DOI: 10.1039/C7CC06064E

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