Issue 14, 2018
From the journal:

Chemical Communications

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks†

Kang Zhang,a   Yunjun Shen,a   Jiyong Liu,a   Bernhard Spinglerb  and  Simon Duttwyler ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Zhejiang University, Zheda Road 38, Hangzhou, P. R. China
E-mail: duttwyler@zju.edu.cn

b Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland

Abstract

The crystal structure of the deprotonated monocarba-closo-dodecaborate [12-CN-CB11H11]− is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C–[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

Graphical abstract: Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

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Article information

DOI
https://doi.org/10.1039/C7CC07724F
Article type
Communication
Submitted
05 Oct 2017
Accepted
22 Dec 2017
First published
22 Dec 2017

Chem. Commun., 2018,54, 1698-1701

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Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

K. Zhang, Y. Shen, J. Liu, B. Spingler and S. Duttwyler, Chem. Commun., 2018, 54, 1698 DOI: 10.1039/C7CC07724F

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