Issue 6, 2018
From the journal:

Chemical Communications

Thermally activated delayed fluorescence of a Zr-based metal–organic framework†

H. Mieno, ORCID logo a   R. Kabe, ORCID logo *ab   M. D. Allendorf ORCID logo c  and  C. Adachi ORCID logo *abd  

* Corresponding authors

a Center for Organic Photonics and Electronics Research (OPERA), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: kabe@opera.kyushu-u.ac.jp

b JST, ERATO, Adachi Molecular Exciton Engineering Project, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: adachi@cstf.kyushu-u.ac.jp

c Sandia National Laboratories, Livermore, CA 94551, USA

d International Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

The first metal–organic framework exhibiting thermally activated delayed fluorescence (TADF) was developed. The zirconium-based framework (UiO-68-dpa) uses a newly designed linker composed of a terphenyl backbone, an electron-accepting carboxyl group, and an electron-donating diphenylamine and exhibits green TADF emission with a photoluminescence quantum yield of 30% and high thermal stability.

Graphical abstract: Thermally activated delayed fluorescence of a Zr-based metal–organic framework

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC08595H
Article type
Communication
Submitted
08 Nov 2017
Accepted
22 Dec 2017
First published
22 Dec 2017

Chem. Commun., 2018,54, 631-634

Permissions

Request permissions

Thermally activated delayed fluorescence of a Zr-based metal–organic framework

H. Mieno, R. Kabe, M. D. Allendorf and C. Adachi, Chem. Commun., 2018, 54, 631 DOI: 10.1039/C7CC08595H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements