A novel parent BN-benzo[c]phenanthrene, with helical chirality and remarkable structural features, has been easily obtained in three steps with a global yield of 55%. Moreover, Cl-substituted derivatives have been prepared and these have served as useful starting materials for the development of palladium-catalyzed cross-coupling reactions.
![Graphical abstract: Synthesis of functionalized helical BN-benzo[c]phenanthrenes](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C7CC09264D&imageInfo.ImageIdentifier.Year=2018)
A. Abengózar, P. García-García, D. Sucunza, A. Pérez-Redondo and J. J. Vaquero, Chem. Commun., 2018, 54, 2467 DOI: 10.1039/C7CC09264D
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