Issue 17, 2018
From the journal:

Chemical Communications

Controlling orthogonal self-assembly through cis–trans isomerization of a non-covalent palladium complex dimer†

Zoran Kokan, ORCID logo *a   Borislav Kovačević, ORCID logo b   Zoran Štefanić, ORCID logo b   Pavleta Tzvetkova ORCID logo c  and  Srećko I. Kirin ORCID logo *a  

* Corresponding authors

a Division of Materials Chemistry, Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia
E-mail: Zoran.Kokan@irb.hr, Srecko.Kirin@irb.hr

b Division of Physical Chemistry, Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia

c Institute for Biological Interfaces 4 – Magnetic Resonance, and Institute of Organic Chemistry, Karlsruhe Institute of Technology, P.O. Box 3640, 76021 Karlsruhe, Germany

Abstract

The trans-configured square-planar complex of dichloropalladium and chiral monodentate phosphine ligands forms self-complementary dimers through 16 hydrogen bonded amides and π–π stacking in chlorinated solvents. The self-assembly is controlled by cis–trans isomerisation of the metal center, where the trans-configuration governs the dimer formation.

Graphical abstract: Controlling orthogonal self-assembly through cis–trans isomerization of a non-covalent palladium complex dimer

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Article information

DOI
https://doi.org/10.1039/C7CC09537F
Article type
Communication
Submitted
13 Dec 2017
Accepted
29 Dec 2017
First published
02 Jan 2018

Chem. Commun., 2018,54, 2094-2097

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Controlling orthogonal self-assembly through cis–trans isomerization of a non-covalent palladium complex dimer

Z. Kokan, B. Kovačević, Z. Štefanić, P. Tzvetkova and S. I. Kirin, Chem. Commun., 2018, 54, 2094 DOI: 10.1039/C7CC09537F

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