Synthesis and characterization of an Fe(I) cage complex with high stability towards strong H-acids

Yan Z. Voloshin; Valentin V. Novikov; Yulia V. Nelyubina; Alexander S. Belov; Dmitrii M. Roitershtein; Anton Savitsky; Andriy Mokhir; Jörg Sutter; Matthias E. Miehlich; Karsten Meyer

doi:10.1039/C7CC09611A

Synthesis and characterization of an Fe(i) cage complex with high stability towards strong H-acids†

Yan Z. Voloshin,

*^ab Valentin V. Novikov,

^a Yulia V. Nelyubina,

^ab Alexander S. Belov,

^a Dmitrii M. Roitershtein,

^c Anton Savitsky,

^d Andriy Mokhir,^e Jörg Sutter,^e Matthias E. Miehlich^e and Karsten Meyer

*^e

Author affiliations

* Corresponding authors

^a Nesmeyanov Institute of Organoelement Compounds RAS, Moscow, Russia
E-mail: voloshin@ineos.ac.ru
Fax: +7(499)135-5085

^b Kurnakov Institute of General and Inorganic Chemistry RAS, Moscow, Russia

^c Zelinsky Institute of Organic Chemistry RAS, Moscow, Russia

^d Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Germany

^e Inorganic Chemistry, Department of Chemistry and Pharmacy, Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Erlangen 91058, Germany
E-mail: karsten.meyer@fau.de

Abstract

The first synthesized and X-ray structurally characterized “classical” iron(I) dioximate showed an unrivaled stability towards strong acids, thus calling for a reassessment of the origins of the electrocatalytic activity of similar low-valent cobalt and iron cage complexes with electron-withdrawing ribbed substituents, shown previously to be effective electrocatalysts of the HER.

Chemical Communications

Synthesis and characterization of an Fe(i) cage complex with high stability towards strong H-acids†

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Synthesis and characterization of an Fe(I) cage complex with high stability towards strong H-acids

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