Retracted Article: Ni2[LnCl6] (Ln = EuII, CeII, GdII): the first LnII compounds stabilized in a pure inorganic lattice

Bianca Baldo; Francisco Rubio; Erwin Flores; Andres Vega; Nathalie Audebrand; Diego Venegas-Yazigi; Verónica Paredes-García

doi:10.1039/C7CC09921E

Retracted Article: Ni₂[LnCl₆] (Ln = Eu^II, Ce^II, Gd^II): the first Ln^II compounds stabilized in a pure inorganic lattice†

Bianca Baldo,^ab Francisco Rubio,^ac Erwin Flores,^a Andres Vega,

^ac Nathalie Audebrand,

^b Diego Venegas-Yazigi

^cd and Verónica Paredes-García

*^ac

Author affiliations

* Corresponding authors

^a Universidad Andres Bello, Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Santiago, Chile
E-mail: vparedes@unab.cl

^b Université de Rennes 1, Institut des Sciences Chimiques de Rennes, UMR 6226, France

^c CEDENNA, Santiago, Chile

^d Universidad de Santiago de Chile, Facultad de Química y Biología, Departamento de Química de los Materiales, Santiago, Chile

Abstract

Here we report the first examples of 3d–4f compounds based on Ln^II cations. We have obtained a series of Ni₂[LnCl₆] isostructural compounds where Ln^II = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm [3 with combining macron] m space group. Magnetic and optical characterization was also performed on this new class of compounds.

Chemical Communications

Retracted Article: Ni₂[LnCl₆] (Ln = Eu^II, Ce^II, Gd^II): the first Ln^II compounds stabilized in a pure inorganic lattice†

Abstract

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Chemical Communications