Issue 34, 2018
From the journal:

Chemical Communications

Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover†

Jong Won Shin,a   Ah Rim Jeong,a   Sungeun Jeoung,b   Hoi Ri Moon, ORCID logo *b   Yuki Komatsumaru,c   Shinya Hayami, ORCID logo c   Dohyun Moond  and  Kil Sik Min ORCID logo *e  

* Corresponding authors

a Department of Chemistry, Kyungpook National University, Daegu 41566, Republic of Korea

b Department of Chemistry, Ulsan National Institute of Science and Technology, Ulsan 44919, Republic of Korea
E-mail: hoirimoon@unist.ac.kr

c Department of Chemistry, Kumamoto University, Kumamoto 860-8555, Japan

d Beamline Department, Pohang Accelerator Laboratory/POSTECH, Pohang 37673, Republic of Korea

e Department of Chemistry Education, Kyungpook National University, Daegu 41566, Republic of Korea
E-mail: minks@knu.ac.kr

Abstract

We report a three-dimensional Fe(II) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.

Graphical abstract: Three-dimensional iron(ii) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

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Article information

DOI
https://doi.org/10.1039/C8CC00678D
Article type
Communication
Submitted
26 Jan 2018
Accepted
20 Mar 2018
First published
21 Mar 2018

Chem. Commun., 2018,54, 4262-4265

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Three-dimensional iron(II) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

J. W. Shin, A. R. Jeong, S. Jeoung, H. R. Moon, Y. Komatsumaru, S. Hayami, D. Moon and K. S. Min, Chem. Commun., 2018, 54, 4262 DOI: 10.1039/C8CC00678D

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