Sulfonate, sulfide and thiolate ligands into an ultrasmall nanocluster: [Ag40.13Cu13.87S19(tBuS)20(tBuSO3)12]

Sha Yang; Jinsong Chai; Hanbao Chong; Yongbo Song; Haizhu Yu; Manzhou Zhu

doi:10.1039/C8CC00985F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Sulfonate, sulfide and thiolate ligands into an ultrasmall nanocluster: [Ag_40.13Cu_13.87S₁₉(tBuS)₂₀(tBuSO₃)₁₂]†

Sha Yang,^a Jinsong Chai,^a Hanbao Chong,^a Yongbo Song,^a Haizhu Yu^a and Manzhou Zhu

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui, China
E-mail: zmz@ahu.edu.cn

Abstract

A novel Ag–Cu bimetallic nanocluster, Ag_40.13Cu_13.87S₁₉(tBuS)₂₀(tBuSO₃)₁₂, has been synthesized by precise control. The crystal structure reveals that the alloy cluster consists of a Cu₁₀Ag₂S₇ core, a M₄₂(tBuS)₂₀(tBuSO₃)₁₂ shell and another 12 bare S atoms. The sulfonate ligand is observed in NCs for the first time via in situ oxidation of thiolate.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8CC00985F
Article type: Communication
Submitted: 05 Feb 2018
Accepted: 30 Mar 2018
First published: 03 Apr 2018

Download Citation

Chem. Commun., 2018,54, 4314-4316

Permissions

Request permissions

Sulfonate, sulfide and thiolate ligands into an ultrasmall nanocluster: [Ag_40.13Cu_13.87S₁₉(tBuS)₂₀(tBuSO₃)₁₂]

S. Yang, J. Chai, H. Chong, Y. Song, H. Yu and M. Zhu, Chem. Commun., 2018, 54, 4314 DOI: 10.1039/C8CC00985F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications