Issue 40, 2018
From the journal:

Chemical Communications

Carbohydrate binding through first- and second-sphere coordination within aromatic oligoamide metallofoldamers†

Pedro Mateus, ORCID logo a   Barbara Wicher,b   Yann Ferrand ORCID logo *a  and  Ivan Huc ORCID logo *ac  

* Corresponding authors

a Université de Bordeaux, CNRS, Bordeaux Institut National Polytechnique, CBMN (UMR 5248), IECB, 2 rue Robert Escarpit, F-33600 Pessac, France
E-mail: y.ferrand@cbmn.u-bordeaux.fr

b Department of Chemical Technology of Drugs, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland

c Department of Pharmacy, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, D-81377 München, Germany
E-mail: ivan.huc@cup.lmu.de

Abstract

Aromatic oligoamide capsules that fold upon metal binding recognize carbohydrate guests in solution as evidenced by CD and NMR titrations. Crystallographic data reveal that, besides their structural role, metal ions also contribute to guest recognition through either first- or second-sphere coordination.

Graphical abstract: Carbohydrate binding through first- and second-sphere coordination within aromatic oligoamide metallofoldamers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC02360C
Article type
Communication
Submitted
25 Mar 2018
Accepted
19 Apr 2018
First published
19 Apr 2018

Chem. Commun., 2018,54, 5078-5081

Permissions

Request permissions

Carbohydrate binding through first- and second-sphere coordination within aromatic oligoamide metallofoldamers

P. Mateus, B. Wicher, Y. Ferrand and I. Huc, Chem. Commun., 2018, 54, 5078 DOI: 10.1039/C8CC02360C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements