Issue 50, 2018
From the journal:

Chemical Communications

Proton and ammonia intercalation into layered iron chalcogenides†

Xiuquan Zhou, ORCID logo ab   Brandon Wilfong,ab   Sz-Chian Liou,c   Halyna Hodovanets,b   Craig M. Brown ORCID logo d  and  Efrain E. Rodriguez ORCID logo *ab  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA
E-mail: efrain@umd.edu

b Center for Nanophysics and Advanced Materials, Department of Physics, University of Maryland, College Park, MD 20742, USA

c AIM Lab, Maryland NanoCenter, University of Maryland, College Park, MD 20742, USA

d NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA

Abstract

Structurally related to the iron-based superconductors, two new intercalated iron chalcogenides (H0.5NH3)Fe2Ch2 where Ch = S, Se have been prepared. By topochemical conversion, the protons were exchanged by lithium to form (Li0.5NH3)Fe2Ch2. Hydrogen bonding plays a significant role in the guest–host interactions of these intercalated phases.

Graphical abstract: Proton and ammonia intercalation into layered iron chalcogenides

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Article information

DOI
https://doi.org/10.1039/C8CC02436G
Article type
Communication
Submitted
27 Mar 2018
Accepted
30 Apr 2018
First published
02 May 2018

Chem. Commun., 2018,54, 6895-6898

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Proton and ammonia intercalation into layered iron chalcogenides

X. Zhou, B. Wilfong, S. Liou, H. Hodovanets, C. M. Brown and E. E. Rodriguez, Chem. Commun., 2018, 54, 6895 DOI: 10.1039/C8CC02436G

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