Bimodal coordination of fused arenes to a Pd3 cluster site

Tsuyoshi Sugawa; Koji Yamamoto; Tetsuro Murahashi

doi:10.1039/C8CC02880J

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Bimodal coordination of fused arenes to a Pd₃ cluster site†

Tsuyoshi Sugawa,^a Koji Yamamoto^a and Tetsuro Murahashi

*^a

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^a Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology O-okayama, Meguro-ku, Tokyo 152-8552, Japan
E-mail: mura@apc.titech.ac.jp
Fax: +81 3 5734 2139
Tel: +81 3 5734 2148

Abstract

We report bimodal coordination behaviour of fused arenes at a Pd₃ cluster site. A cyclooctatetraene-supported Pd₃ cluster accommodates anthracene and tetracene in an oxidative π-addition manner, whereas triphenylene and fluoranthene are accommodated in a π-coordination manner.

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Article information

DOI: https://doi.org/10.1039/C8CC02880J
Article type: Communication
Submitted: 11 Apr 2018
Accepted: 14 May 2018
First published: 22 May 2018

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Chem. Commun., 2018,54, 5875-5878

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Bimodal coordination of fused arenes to a Pd₃ cluster site

T. Sugawa, K. Yamamoto and T. Murahashi, Chem. Commun., 2018, 54, 5875 DOI: 10.1039/C8CC02880J

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Chemical Communications