Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network

Shi-Qiang Wang; Qing-Yuan Yang; Soumya Mukherjee; Daniel O’Nolan; Ewa Patyk-Kaźmierczak; Kai-Jie Chen; Mohana Shivanna; Claire Murray; Chiu C. Tang; Michael J. Zaworotko

doi:10.1039/C8CC03838D

Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network†

Shi-Qiang Wang,

^a Qing-Yuan Yang,

^a Soumya Mukherjee,

^a Daniel O’Nolan,

^a Ewa Patyk-Kaźmierczak,^a Kai-Jie Chen,

^a Mohana Shivanna,^a Claire Murray,^b Chiu C. Tang^b and Michael J. Zaworotko

*^a

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* Corresponding authors

^a Department of Chemical Sciences, Bernal Institute, University of Limerick, Limerick, Republic of Ireland
E-mail: Michael.Zaworotko@ul.ie

^b Diamond Light Source, Harwell Science and Innovation Campus, Didcot OX11 0DE, UK

Abstract

A nonporous square lattice (sql) coordination network [Co(bipy)₂(NCS)₂]_n (sql-1-Co-NCS) exhibits recyclable switching induced by CO₂. The sorption isotherms are stepped with moderate hysteresis, temperature controlled and saturation uptake is fixed. Such switching, which has rarely been observed, offers the promise of exceptional working capacity for gas storage.

Chemical Communications

Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network†

Abstract

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Recyclable switching between nonporous and porous phases of a square lattice (sql) topology coordination network

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