A carbonaceous two-dimensional lattice with FeN4 units

Jun Maruyama; Taiji Amano; Satoshi Inoue; Yasuji Muramatsu; Noriko Yoshizawa; Eric M. Gullikson

doi:10.1039/C8CC04424D

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A carbonaceous two-dimensional lattice with FeN₄ units†

Jun Maruyama,

*^a Taiji Amano,^b Satoshi Inoue,^b Yasuji Muramatsu,^b Noriko Yoshizawa^c and Eric M. Gullikson^d

Author affiliations

* Corresponding authors

^a Research Division of Environmental Technology, Osaka Research Institute of Industrial Science and Technology, 1-6-50, Morinomiya, Joto-ku, Osaka 536-8553, Japan
E-mail: maruyama@omtri.or.jp

^b Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2201, Japan

^c Department of Energy and Environment, National Institute of Advanced Industrial Science and Technology, 16-1, Onogawa, Tsukuba 305-8569, Japan

^d Center for X-ray Optics, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, USA

Abstract

A metal-containing carbonaceous two-dimensional lattice was formed on a graphene plane by sublimation, deposition, and pyrolysis of Fe phthalocyanine (Pc). The formation and growth of the FePc-derived π-conjugated planar system were reflected by its orientation conversion from the perpendicular to horizontal mode and by the N K-edge X-ray absorption near-edge structure.

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Article information

DOI: https://doi.org/10.1039/C8CC04424D
Article type: Communication
Submitted: 02 Jun 2018
Accepted: 27 Jun 2018
First published: 27 Jun 2018

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Chem. Commun., 2018,54, 8995-8998

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A carbonaceous two-dimensional lattice with FeN₄ units

J. Maruyama, T. Amano, S. Inoue, Y. Muramatsu, N. Yoshizawa and E. M. Gullikson, Chem. Commun., 2018, 54, 8995 DOI: 10.1039/C8CC04424D

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Chemical Communications