Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

Ariane Brandenburg; Denis S. Krylov; Alexander Beger; Anja U. B. Wolter; Bernd Büchner; Alexey A. Popov

doi:10.1039/C8CC04736G

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Carbide clusterfullerene DyYTiC@C₈₀ featuring three different metals in the endohedral cluster and its single-ion magnetism†

Ariane Brandenburg,

^a Denis S. Krylov,^a Alexander Beger,^a Anja U. B. Wolter,^a Bernd Büchner^a and Alexey A. Popov

*^a

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* Corresponding authors

^a Leibniz Institute for Solid State and Materials Research (IFW), D-01069 Dresden, Germany
E-mail: a.popov@ifw-dresden.de

Abstract

Carbide clusterfullerene DyYTiC@C₈₀-I_h with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C₈₀ are compared to those of DySc₂N@C₈₀ and the influence of the central atom in the endohedral cluster is analyzed.

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Article information

DOI: https://doi.org/10.1039/C8CC04736G
Article type: Communication
Submitted: 13 Jun 2018
Accepted: 26 Jul 2018
First published: 26 Jul 2018
This article is Open Access

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Chem. Commun., 2018,54, 10683-10686

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Carbide clusterfullerene DyYTiC@C₈₀ featuring three different metals in the endohedral cluster and its single-ion magnetism

A. Brandenburg, D. S. Krylov, A. Beger, A. U. B. Wolter, B. Büchner and A. A. Popov, Chem. Commun., 2018, 54, 10683 DOI: 10.1039/C8CC04736G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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Chemical Communications