Highly efficient and selective visible-light driven CO2-to-CO conversion by a Co-based cryptate in H2O/CH3CN solution

Dong-Cheng Liu; Hong-Juan Wang; Jia-Wei Wang; Di-Chang Zhong; Long Jiang; Tong-Bu Lu

doi:10.1039/C8CC04892D

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Highly efficient and selective visible-light driven CO₂-to-CO conversion by a Co-based cryptate in H₂O/CH₃CN solution†

Dong-Cheng Liu,^a Hong-Juan Wang,^b Jia-Wei Wang,

^a Di-Chang Zhong,

*^b Long Jiang*^a and Tong-Bu Lu

*^ab

Author affiliations

* Corresponding authors

^a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: lutongbu@mail.sysu.edu.cn, cesjl@mail.sysu.edu.cn

^b Institute for New Energy Materials & Low Carbon Technologies, School of Material Science & Engineering, Tianjin University of Technology, Tianjin 300384, China
E-mail: zhong_dichang@hotmail.com

Abstract

Herein, we report a mononuclear Co(II) cryptate which exhibits highly efficient and selective photocatalytic CO₂-to-CO conversion in H₂O/CH₃CN solution. The TON and selectivity reach as high as 51 392 and 98%, respectively.

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Article information

DOI: https://doi.org/10.1039/C8CC04892D
Article type: Communication
Submitted: 19 Jun 2018
Accepted: 13 Sep 2018
First published: 14 Sep 2018

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Chem. Commun., 2018,54, 11308-11311

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Highly efficient and selective visible-light driven CO₂-to-CO conversion by a Co-based cryptate in H₂O/CH₃CN solution

D. Liu, H. Wang, J. Wang, D. Zhong, L. Jiang and T. Lu, Chem. Commun., 2018, 54, 11308 DOI: 10.1039/C8CC04892D

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Chemical Communications