Anthranilamide (aam)-substituted diboron: palladium-catalyzed selective B(aam) transfer

Abstract

An unsymmetrical diboron bearing an anthranilamide (aam) substituent was synthesized and was found to be coupled with aryl halides through the palladium-catalyzed Miyaura–Ishiyama-type reaction. The selective transfer of aam-substituted boryl moiety led to exclusive formation of diverse Ar–B(aam).