Issue 77, 2018

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Abstract

We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(III) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

Graphical abstract: Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

Supplementary files

Article information

Article type
Communication
Submitted
12 Jul 2018
Accepted
14 Aug 2018
First published
14 Aug 2018

Chem. Commun., 2018,54, 10824-10827

Author version available

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

I. Ling, H. Kumari, M. Mirzamani, A. N. Sobolev, C. J. Garvey, J. L. Atwood and C. L. Raston, Chem. Commun., 2018, 54, 10824 DOI: 10.1039/C8CC05650A

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