Issue 72, 2018
From the journal:

Chemical Communications

Reversible structural transformation induced switchable single-molecule magnet behavior in lanthanide metal–organic frameworks†

Mengmeng Wang,a   Xixi Meng,a   Fen Song,a   Yanfei He,a   Wei Shi, ORCID logo *a   Hongling Gao,*b   Jinkui Tang ORCID logo c  and  Cheng Peng ORCID logo *ade  

* Corresponding authors

a Department of Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
E-mail: shiwei@nankai.edu.cn, pcheng@nankai.edu.cn

b Department of Chemistry, Tianjin University, Tianjin 300354, China
E-mail: ghl@tju.edu.cn

c State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

d State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

e Collaborative Innovation Center of Chemistry Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Abstract

Switchable “on/off” single-molecule magnet (SMM) behavior can be realized in lanthanide metal–organic frameworks (Ln-MOFs) tuned by the temperature-induced change of the coordination geometry of the lanthanide centers.

Graphical abstract: Reversible structural transformation induced switchable single-molecule magnet behavior in lanthanide metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C8CC06058D
Article type
Communication
Submitted
26 Jul 2018
Accepted
10 Aug 2018
First published
10 Aug 2018

Chem. Commun., 2018,54, 10183-10186

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Reversible structural transformation induced switchable single-molecule magnet behavior in lanthanide metal–organic frameworks

M. Wang, X. Meng, F. Song, Y. He, W. Shi, H. Gao, J. Tang and C. Peng, Chem. Commun., 2018, 54, 10183 DOI: 10.1039/C8CC06058D

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