Issue 81, 2018

Exogenous-oxidant-free electrochemical oxidative C–H sulfonylation of arenes/heteroarenes with hydrogen evolution

Abstract

An efficient and environmentally benign electrochemical oxidative radical C–H sulfonylation of arenes/heteroarenes was developed in this work. A series of significant diarylsulfones were prepared under mild catalyst- and exogenous-oxidant-free reaction conditions, which efficiently avoid the issues of desulfonylation or over-reduction of sulfonyl groups.

Graphical abstract: Exogenous-oxidant-free electrochemical oxidative C–H sulfonylation of arenes/heteroarenes with hydrogen evolution

Supplementary files

Article information

Article type
Communication
Submitted
08 Aug 2018
Accepted
07 Sep 2018
First published
26 Sep 2018

Chem. Commun., 2018,54, 11471-11474

Exogenous-oxidant-free electrochemical oxidative C–H sulfonylation of arenes/heteroarenes with hydrogen evolution

Y. Yuan, Y. Yu, J. Qiao, P. Liu, B. Yu, W. Zhang, H. Liu, M. He, Z. Huang and A. Lei, Chem. Commun., 2018, 54, 11471 DOI: 10.1039/C8CC06451B

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