Issue 92, 2018
From the journal:

Chemical Communications

Carbocation catalysed ring closing aldehyde–olefin metathesis†

Shengjun Ni ORCID logo a  and  Johan Franzén ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Organic Chemistry, Royal Institute of Technology (KTH), Teknikringen 30, SE-100 44 Stockholm, Sweden
E-mail: jfranze@kth.se

Abstract

A highly efficient aldehyde–olefin metathesis catalysed by the carbocation, 4-phenylphenyl-diphenylmethylium ion, has been developed. This protocol is characterized by high yields, low catalyst loading (down to 2 mol%), good functional group compatibility and mild reaction conditions.

Graphical abstract: Carbocation catalysed ring closing aldehyde–olefin metathesis

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Article information

DOI
https://doi.org/10.1039/C8CC06734A
Article type
Communication
Submitted
18 Aug 2018
Accepted
24 Oct 2018
First published
25 Oct 2018
This article is Open Access
Creative Commons BY license

Chem. Commun., 2018,54, 12982-12985

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Carbocation catalysed ring closing aldehyde–olefin metathesis

S. Ni and J. Franzén, Chem. Commun., 2018, 54, 12982 DOI: 10.1039/C8CC06734A

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