Issue 86, 2018
From the journal:

Chemical Communications

A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles†

Bin-Qing He,a   Xiao-Ye Yu,a   Peng-Zi Wang,a   Jia-Rong Chen ORCID logo *a  and  Wen-Jing Xiao ORCID logo ab  

* Corresponding authors

a CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
E-mail: chenjiarong@mail.ccnu.edu.cn, wxiao@mail.ccnu.edu.cn

b Hubei Key Laboratory of Processing and Application of Catalytic Materials, Huanggang Normal University, Huanggang, Hubei 438000, China

Abstract

A photoredox-catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of cycloketone oxime esters and styrenes in DMSO is described. This three-component, one-pot procedure features mild conditions, a broad substrate scope, and high functional group tolerance, providing an efficient approach to access diversely functionalized ketonitriles.

Graphical abstract: A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

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Article information

DOI
https://doi.org/10.1039/C8CC07072E
Article type
Communication
Submitted
31 Aug 2018
Accepted
08 Oct 2018
First published
08 Oct 2018

Chem. Commun., 2018,54, 12262-12265

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A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

B. He, X. Yu, P. Wang, J. Chen and W. Xiao, Chem. Commun., 2018, 54, 12262 DOI: 10.1039/C8CC07072E

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