Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn(ii) coordination polymer†
Alexander D.
Volodin, 
a
Alexander A.
Korlyukov,
ab
Ekaterina N.
Zorina-Tikhonova,
c
Aleksandr S.
Chistyakov,
c
Igor L.
Eremenko
ac
and
Anna V.
Vologzhanina
*a
a
Alexander A.
Korlyukov,
ab
Ekaterina N.
Zorina-Tikhonova,
c
Aleksandr S.
Chistyakov,
c
Igor L.
Eremenko
ac
and
Anna V.
Vologzhanina
*a
Abstract
1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal–organic framework (MOF) [Zn2(H2O)2(Amal)2(bpe)] to produce a 3D MOF with a new topology.
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