Issue 32, 2018
From the journal:

CrystEngComm

Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies†

Luke C. Delmas, ORCID logo a   Andrew J. P. White,a   David Pugh, ORCID logo a   Peter N. Horton,b   Simon J. Coles, ORCID logo b   Paul D. Lickiss ORCID logo *a  and  Robert P. Davies ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: p.lickiss@imperial.ac.uk, r.davies@imperial.ac.uk

b EPSRC Crystallographic Service, Department of Chemistry, University of Southampton, Highfield, Southampton, UK

Abstract

A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(II) gave IMP-20 and with Zn(II) gave IMP-21: both are 3D MOFs incorporating Si–O–Si–O–Si linkages.

Graphical abstract: Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

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Article information

DOI
https://doi.org/10.1039/C8CE00662H
Article type
Communication
Submitted
25 Apr 2018
Accepted
22 Jun 2018
First published
02 Aug 2018
This article is Open Access
Creative Commons BY license

CrystEngComm, 2018,20, 4541-4545

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Trisiloxane-centred metal–organic frameworks and hydrogen bonded assemblies

L. C. Delmas, A. J. P. White, D. Pugh, P. N. Horton, S. J. Coles, P. D. Lickiss and R. P. Davies, CrystEngComm, 2018, 20, 4541 DOI: 10.1039/C8CE00662H

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