Issue 28, 2018
From the journal:

CrystEngComm

Solvent-induced structural transformation and magnetic modulation in 1D copper(ii) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole†

Xiang-Wen Wu,a   Feng Pan,a   Shi Yin,a   Jing-Yuan Ge,b   Guo-Xia Jin,*a   Peng Wangc  and  Jian-Ping Ma ORCID logo *a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, China
E-mail: guoxiajin@sdnu.edu.cn, xxgk123@163.com

b College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, P. R. China

c College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266510, P. R. China

Abstract

A helical Cu(II) polymer 1 exhibits reversible SCSC transformation and magnetism switch by the chemisorption/desorption of MeCN molecules. Significant changes in its color, coordination environment, and magnetic behavior were found during the SCSC transformation. In addition, the effect of different coordinated solvents on the magnetic properties was further investigated.

Graphical abstract: Solvent-induced structural transformation and magnetic modulation in 1D copper(ii) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole

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Article information

DOI
https://doi.org/10.1039/C8CE00820E
Article type
Communication
Submitted
18 May 2018
Accepted
12 Jun 2018
First published
13 Jun 2018

CrystEngComm, 2018,20, 3955-3959

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Solvent-induced structural transformation and magnetic modulation in 1D copper(II) polymers based on a semi-rigid ligand containing 4-amino-1,2,4-triazole

X. Wu, F. Pan, S. Yin, J. Ge, G. Jin, P. Wang and J. Ma, CrystEngComm, 2018, 20, 3955 DOI: 10.1039/C8CE00820E

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