Issue 35, 2018

Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBUs

Abstract

Two new metal–organic framework compounds of composition [M123-O)83-OH)8(μ-OH)6(OH)6(H2O)6(APDC)6], with M = Zr and Hf, denoted as M-CAU-39, containing the azopyridinedicarboxylate ion (APDC2−) as a new linker, were obtained by a water-based synthesis. The crystal structure was determined from powder X-ray diffraction data. The inorganic building unit (IBU) is the dodecanuclear cluster {M12O8(OH)14} and its connection results in a porous two-dimensional network.

Graphical abstract: Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBUs

Supplementary files

Article information

Article type
Communication
Submitted
08 Jun 2018
Accepted
21 Jun 2018
First published
26 Jun 2018

CrystEngComm, 2018,20, 5108-5111

Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBUs

S. Waitschat, H. Reinsch, M. Arpacioglu and N. Stock, CrystEngComm, 2018, 20, 5108 DOI: 10.1039/C8CE00949J

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