Issue 34, 2018
From the journal:

CrystEngComm

A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption†

Xiang Gao,b   Shan-Shan Zhang,b   Hui Yan,a   Yun-Wu Li, ORCID logo *a   Qing-Yun Liu, ORCID logo c   Xing-Po Wang,*b   Chen-Ho Tung,b   Hui-Yan Maa  and  Di Sun ORCID logo *ab  

* Corresponding authors

a Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology and, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, P. R. China
E-mail: lyw5251851@163.com, liyunwu@lcu.edu.cn

b Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China
E-mail: dsun@sdu.edu.cn

c College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, People's Republic of China

Abstract

A pillar-layered microporous MOF (SD/Co3) has been constructed from trimeric {Co3(COO)6} clusters as SBUs and mixed ligands as linkers. It exhibits preferential selective adsorption of C2H2/C2H4, C2H2/C2H6 and CO2/N2, owing to its dual active sites including uncoordinated nitrogen sites from pyrimidine groups and unsaturated metal centres (UMCs) exposed in channels.

Graphical abstract: A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption

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Article information

DOI
https://doi.org/10.1039/C8CE01118D
Article type
Communication
Submitted
08 Jul 2018
Accepted
02 Aug 2018
First published
04 Aug 2018

CrystEngComm, 2018,20, 4905-4909

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A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption

X. Gao, S. Zhang, H. Yan, Y. Li, Q. Liu, X. Wang, C. Tung, H. Ma and D. Sun, CrystEngComm, 2018, 20, 4905 DOI: 10.1039/C8CE01118D

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