Issue 10, 2018
From the journal:

Dalton Transactions

Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(iv) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes†

Ramona Turcas,a   Dóra Lakk-Bogáth,a   Gábor Speiera  and  József Kaizer ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Pannonia, H-8201 Veszprém, Hungary
E-mail: kaizer@almos.vein.hu

Abstract

The present study describes the first example of the hydroxylation of benzaldehydes by synthetic nonheme oxoiron(IV) complexes, where the reactivity, chemoselectivity, and mechanism were strongly influenced by the ligand environment of the iron center.

Graphical abstract: Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(iv) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

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Article information

DOI
https://doi.org/10.1039/C7DT03727A
Article type
Communication
Submitted
04 Oct 2017
Accepted
25 Jan 2018
First published
05 Feb 2018

Dalton Trans., 2018,47, 3248-3252

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Steric control and the mechanism of benzaldehyde oxidation by polypyridyl oxoiron(IV) complexes: aromatic versus benzylic hydroxylation of aromatic aldehydes

R. Turcas, D. Lakk-Bogáth, G. Speier and J. Kaizer, Dalton Trans., 2018, 47, 3248 DOI: 10.1039/C7DT03727A

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