M. D. Straub, S. Hohloch, S. G. Minasian and J. Arnold
Dalton Trans., 2018,47, 1772-1776
DOI:
10.1039/C7DT04813K,
Communication
The syntheses of the first homoleptic U(III) and U(IV) amidate complexes are described. These can be interconverted by chemical reduction/oxidation, showing an unusual change in coordination number from four in the U(III) complex to eight in the U(IV) complex in the solid state structures.
