Issue 17, 2018
From the journal:

Dalton Transactions

Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates†

Daniel Werner, ORCID logo a   Uwe Bayer, ORCID logo a   Nazli E. Rad,b   Peter C. Junk, ORCID logo *b   Glen B. Deacon ORCID logo *c  and  Reiner Anwander ORCID logo *a  

* Corresponding authors

a Institut für Anorganische Chemie, University of Tübingen (EKUT), Auf der Morgenstelle 18, Germany
E-mail: reiner.anwander@uni-tuebingen.de

b College of Science & Engineering, James Cook University, Townsville, Qld, Australia

c School of Chemistry, Monash University, Clayton, Victoria 3800, Australia

Abstract

Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ–η2:η5-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η5:η5 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.

Graphical abstract: Unique and contrasting structures of homoleptic lanthanum(iii) and cerium(iii) 3,5-dimethylpyrazolates

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Article information

DOI
https://doi.org/10.1039/C8DT00338F
Article type
Communication
Submitted
25 Jan 2018
Accepted
04 Apr 2018
First published
09 Apr 2018

Dalton Trans., 2018,47, 5952-5955

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Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates

D. Werner, U. Bayer, N. E. Rad, P. C. Junk, G. B. Deacon and R. Anwander, Dalton Trans., 2018, 47, 5952 DOI: 10.1039/C8DT00338F

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