Issue 16, 2018

A novel route with a Cu(ii)-MOF-derived structure to synthesize Cu/Cu2O NPs@graphene: the electron transfer leads to the synergistic effect of the Cu(0)–Cu(i) phase for an effective catalysis of the Sonogashira cross-coupling reactions

Abstract

A uniformly dispersed two-phase Cu/Cu2O NPs@graphene was obtained via an innovative “take” and “off” synthesis strategy with a Cu-MOF-derived jacket structure. The electron transfer between the Cu phase and Cu2O phase leads to the synergistic effect of the Cu(0)–Cu(I) phase for an efficient catalysis of the Sonogashira cross-coupling reactions.

Graphical abstract: A novel route with a Cu(ii)-MOF-derived structure to synthesize Cu/Cu2O NPs@graphene: the electron transfer leads to the synergistic effect of the Cu(0)–Cu(i) phase for an effective catalysis of the Sonogashira cross-coupling reactions

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2018
Accepted
25 Mar 2018
First published
26 Mar 2018

Dalton Trans., 2018,47, 5538-5541

A novel route with a Cu(II)-MOF-derived structure to synthesize Cu/Cu2O NPs@graphene: the electron transfer leads to the synergistic effect of the Cu(0)–Cu(I) phase for an effective catalysis of the Sonogashira cross-coupling reactions

W. Sun, L. Gao, X. Sun and G. Zheng, Dalton Trans., 2018, 47, 5538 DOI: 10.1039/C8DT00465J

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