Issue 30, 2018
From the journal:

Dalton Transactions

Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound†

Xiao-Quan Zhu,a   Shao-Dong Su,ab   Yue-Hong Wen,a   Lin-Tao Zhang,ab   Yu-Ying Yang,ab   Xin-Tao Wu ORCID logo a  and  Tian-Lu Sheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: tsheng@fjirsm.ac.cn

b School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, China

Abstract

A trinuclear cyanide-bridged luminescent compound, trans-RuII(DMAP)4(CN)2[(PY5Me2)Mn]2[PF6]4 (1-R), and its oxidation product, ferromagnetic trans-RuIII(DMAP)4(CN)2[(PY5Me2)Mn]2-[PF6]5 (1-O), were synthesized and fully characterized. This is the first example of a molecular material showing a redox-controlled transformation between fluorescence and ferromagnetism.

Graphical abstract: Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

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Article information

DOI
https://doi.org/10.1039/C8DT01905C
Article type
Communication
Submitted
11 May 2018
Accepted
22 Jun 2018
First published
27 Jun 2018

Dalton Trans., 2018,47, 9985-9988

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Redox-induced switch between luminescence and magnetism in a trinuclear cyanide-bridged compound

X. Zhu, S. Su, Y. Wen, L. Zhang, Y. Yang, X. Wu and T. Sheng, Dalton Trans., 2018, 47, 9985 DOI: 10.1039/C8DT01905C

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