Issue 45, 2018
From the journal:

Dalton Transactions

A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sites†

Takashi Yoshimura, ORCID logo *ab   Kojiro Nagata,a   Tatsuki Shiroyama,c   Yasushi Kino,d   Tsutomu Takayama,e   Tsutomu Sekinef  and  Atsushi Shinoharabc  

* Corresponding authors

a Radioisotope Research Center, Institute for Radiation Sciences, Osaka University, Suita, Osaka 565-0871, Japan
E-mail: tyoshi@rirc.osaka-u.ac.jp

b Project Research Center for Fundamental Sciences, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan

c Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan

d Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Miyagi 980-8576, Japan

e Department of Chemistry, Daido University, Nagoya, Aichi 457-8530, Japan

f Institute for Excellence in Higher Education, Tohoku University, Sendai, Miyagi 980-8576, Japan

Abstract

A novel, luminescent technetium complex, [TcN(CN)2bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.

Graphical abstract: A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sites

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Article information

DOI
https://doi.org/10.1039/C8DT02935K
Article type
Communication
Submitted
19 Jul 2018
Accepted
21 Sep 2018
First published
27 Sep 2018

Dalton Trans., 2018,47, 16027-16030

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A luminescent dicyanidonitridotechnetium(V) core with tridentate ligand coordination sites

T. Yoshimura, K. Nagata, T. Shiroyama, Y. Kino, T. Takayama, T. Sekine and A. Shinohara, Dalton Trans., 2018, 47, 16027 DOI: 10.1039/C8DT02935K

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