Issue 38, 2018

Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst

Abstract

A practical, efficient and environmentally benign catalytic protocol for the oxidative cross-coupling reaction of halides with amines, oxidative self-coupling of amines and oxidation of halides was developed with inorganic-ligand supported ZnPOM (NH4)4[ZnMo6O18(OH)6] using molecular oxygen. This method mainly utilizes an inorganic polymolybdate ligand to support the Zn2+ ion, avoiding the use of complicated organic ligands.

Graphical abstract: Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst

Supplementary files

Article information

Article type
Communication
Submitted
23 Jul 2018
Accepted
21 Aug 2018
First published
05 Sep 2018

Dalton Trans., 2018,47, 13323-13327

Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst

J. Wang, Y. Zhai, Y. Wang, H. Yu, W. Zhao and Y. Wei, Dalton Trans., 2018, 47, 13323 DOI: 10.1039/C8DT03003K

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