Issue 46, 2018

PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

Abstract

Polar rosiaite-type germanate PbTeGeO6 (PTGO) was grown from TeO2 flux. It exhibits a two dimensional layered structure composed of [TeGeO6]2− sheets with Pb2+ separation between the sheets. The second harmonic generation intensity of the title compound is about 1.5 times that of KH2PO4. The first principles calculation was performed to investigate its electronic structure, refractive indices and nonlinear optical properties.

Graphical abstract: PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

Supplementary files

Article information

Article type
Communication
Submitted
01 Aug 2018
Accepted
06 Sep 2018
First published
10 Sep 2018

Dalton Trans., 2018,47, 16388-16392

PbTeGeO6: polar rosiaite-type germanate featuring a two dimensional layered structure

Z. Jia, X. Jiang, Z. Lin and M. Xia, Dalton Trans., 2018, 47, 16388 DOI: 10.1039/C8DT03136C

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