Issue 15, 2018
From the journal:

Green Chemistry

Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes†

Yunfei Tian,a   Anbo Ling,b   Ren Fang,b   Ren Xiang Tana  and  Zhong-Quan Liu ORCID logo *ab  

* Corresponding authors

a State Key Laboratory Cultivation Base for TCM Quality and Efficacy, College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023, China
E-mail: liuzq@njucm.edu.cn

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Abstract

A Cu(II)-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp3)–H bond cleavage was achieved. This reaction features high site-selectivity diverse functional group tolerance, and scalability.

Graphical abstract: Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes

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Article information

DOI
https://doi.org/10.1039/C8GC01394B
Article type
Communication
Submitted
03 May 2018
Accepted
20 Jun 2018
First published
20 Jun 2018

Green Chem., 2018,20, 3432-3435

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Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes

Y. Tian, A. Ling, R. Fang, R. X. Tan and Z. Liu, Green Chem., 2018, 20, 3432 DOI: 10.1039/C8GC01394B

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