Issue 3, 2018

Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

Abstract

Herein, a copper/TBHP catalyst system for the α-C–H acyloxylation of carbonyl compounds is developed using terminal alkynes as the acyloxy source. A variety of carbonyl compounds and terminal alkynes are tolerated in this reaction. In addition, its possible mechanism is proposed.

Graphical abstract: Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

Supplementary files

Article information

Article type
Letter
Submitted
16 Oct 2017
Accepted
21 Dec 2017
First published
05 Jan 2018

New J. Chem., 2018,42, 1581-1584

Copper-catalyzed α-C–H acyloxylation of carbonyl compounds with terminal alkynes

J. Li, Z. Yang, T. Yang, J. Yi and C. Zhou, New J. Chem., 2018, 42, 1581 DOI: 10.1039/C7NJ03989A

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