Piezo-phototronic mediated enhanced photodetection characteristics of plasmonic Au-g-C3N4/CdS/ZnO based hybrid heterojunctions on a flexible platform

Abstract

We have studied the piezo-phototronic induced enhancement in the photo-response of CdS/ZnO heterojunctions attached with plasmonic Au nanoparticle loaded 2D-graphitic carbon nitride (g-C₃N₄). The hybrid g-C₃N₄/CdS/ZnO heterojunction favours the charge carrier separation through the formation of a step-like band alignment. Furthermore, the integration of plasmonic Au loaded g-C₃N₄ nanosheets on the conventional CdS/ZnO heterojunction facilitates improved visible light absorption properties. The heterojunction device on a flexible platform under the application of a strain (∼0.017%) exhibits ∼10² times higher photoresponse over the control sample at a constant bias of ∼2 V. The variation in the photo-response under different bending conditions has been explained in terms of the improved charge transport through the modified energy bands at the interface of ZnO. The improved piezo-phototronic properties originated from the plasmonic properties of Au loaded g-C₃N₄ and the piezoelectric characteristics of c-axis oriented ZnO films may be used for future flexible photonic devices.