Biomimetic synthesis of the bisindole framework present in sciodole, an alkaloid from Tricholoma sciodes†
Abstract
A synthesis of the unique bisindole framework present in the mushroom-derived alkaloid sciodole has been achieved, validating a biosynthesis proposal that the C–N bisindole bond present in the natural product is forged by amination of an azafulvenium.
- This article is part of the themed collection: Synthetic methodology in OBC
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