Issue 2, 2018
From the journal:

Inorganic Chemistry Frontiers

The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(iii) units†

Xuejing Zhang,ac   Na Xu, ORCID logo *a   Wei Shi, ORCID logo a   Bing-Wu Wang ORCID logo b  and  Peng Cheng ORCID logo *ad  

* Corresponding authors

a College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), Nankai University, Tianjin 300071, China
E-mail: pcheng@nankai.edu.cn, naxu@nankai.edu.cn

b Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

c Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, China

d Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

Abstract

We report the synthesis and magnetic properties of a μ2-OH− bridged dinuclear Dy(III) single-molecule magnet (SMM), [Dy2(apca)4(μ2-OH)2(H2O)2]n (Dy, Hapca = 3-aminopyrazine-2-carboxylic acid), which was assembled in a two-dimensional (2D) network. Magnetic studies reveal that Dy exhibits ferromagnetic interactions, multi-process slow relaxation of magnetization and hysteresis loops. The influence of an external magnetic field and magnetic-site dilution on the magnetic properties was also studied.

Graphical abstract: The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(iii) units

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Article information

DOI
https://doi.org/10.1039/C7QI00663B
Article type
Research Article
Submitted
25 Oct 2017
Accepted
06 Dec 2017
First published
06 Dec 2017

Inorg. Chem. Front., 2018,5, 432-437

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The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(III) units

X. Zhang, N. Xu, W. Shi, B. Wang and P. Cheng, Inorg. Chem. Front., 2018, 5, 432 DOI: 10.1039/C7QI00663B

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