Facile synthesis of MoO2/CaSO4 composites as highly efficient adsorbents for congo red and rhodamine B

Abstract

A novel rod-shaped MoO₂/CaSO₄ composite was prepared by using hexa-ammonium molybdate and flue gas desulfurization gypsum via a simple mixed-solvothermal route. In this composite, CaSO₄ matrices are decorated with MoO₂ nanoparticles, and non-structural mesopores are formed via particle packing. Moreover, it displays an excellent adsorption capability towards anionic congo red (CR) and cationic rhodamine B (RhB). The adsorption quantities per unit mass and removal efficiencies of the two dyes are significantly influenced by adsorbent dose, solution pH, and temperature. The adsorption isotherm data can be best fitted by the Langmuir model, and the calculated maximum adsorption quantities at 303.5 K are 853.54 mg g⁻¹ for CR and 86.38 mg g⁻¹ for RhB, respectively, which are superior to other common adsorbents. The corresponding kinetic data can be well matched with the pseudo-second-order model. Additionally, the CR adsorption is an exothermic process, while the RhB adsorption is an endothermic process. Both of them are multi-step chemisorption processes influenced by surface adsorption and intra-particle diffusion. This MoO₂/CaSO₄ composite can be applied as an alternative adsorbent for removing organic dyestuffs from printing and dyeing wastewater.