Issue 13, 2018, Issue in Progress
From the journal:

RSC Advances

Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst†

Lidia Clot-Almenara, ORCID logo a   Carles Rodríguez-Escrich ORCID logo *a  and  Miquel A. Pericàs ORCID logo *ab  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: mapericas@iciq.es

b Departament de Química Inorgànica i Orgànica, Universitat de Barcelona, 08080 Barcelona, Spain

Abstract

A polystyrene-supported BINOL-derived chiral phosphoric acid has been applied to the desymmetrisation of meso-diones to produce enantioenriched cyclohexenones. The catalytic resin has proven highly active and robust, giving rise to Hajos–Parrish or Wieland–Miescher type products in good yields and enantioselectivities, while allowing for extended recycling.

Graphical abstract: Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst

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Article information

DOI
https://doi.org/10.1039/C7RA13471A
Article type
Paper
Submitted
19 Dec 2017
Accepted
04 Feb 2018
First published
12 Feb 2018
This article is Open Access
Creative Commons BY license

RSC Adv., 2018,8, 6910-6914

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Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst

L. Clot-Almenara, C. Rodríguez-Escrich and M. A. Pericàs, RSC Adv., 2018, 8, 6910 DOI: 10.1039/C7RA13471A

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