Issue 13, 2018, Issue in Progress

Nitrogen-doped hierarchical porous carbon derived from a chitosan/polyethylene glycol blend for high performance supercapacitors

Abstract

Nitrogen-doped hierarchical porous carbon (NHPC) materials were synthesized by using a chitosan/polyethylene glycol (PEG) blend as raw material through a facile carbonization–activation process. In this method, chitosan was used as a nitrogen-containing carbon precursor, low cost and large-scale commercial PEG was employed as a porogen. The physical and electrochemical properties of the resultant NHPC were affected by the ratio of chitosan and PEG. The sample obtained by the ratio of 3 : 2 exhibits a high specific surface area (2269 m2 g−1), moderate nitrogen doping (3.22 at%) and optimized pore structure. It exhibits a high specific capacitance of 356 F g−1 in 1 M H2SO4 and 271 F g−1 in 2 M KOH at a current density of 1 A g−1, and over 230 F g−1 can be still retained at a high current density of 20 A g−1 in both electrolytes. Additionally, the assembled symmetric supercapacitors show an excellent cycling stability with 94% (in 1 M H2SO4) and 97% (in 2 M KOH) retention after 10 000 cycles at 1 A g−1. These results indicate that the chitosan/PEG blend can act as a novel and appropriate precursor to prepare low-cost NHPC materials for high-performance supercapacitors.

Graphical abstract: Nitrogen-doped hierarchical porous carbon derived from a chitosan/polyethylene glycol blend for high performance supercapacitors

Article information

Article type
Paper
Submitted
02 Jan 2018
Accepted
05 Feb 2018
First published
14 Feb 2018
This article is Open Access
Creative Commons BY license

RSC Adv., 2018,8, 7072-7079

Nitrogen-doped hierarchical porous carbon derived from a chitosan/polyethylene glycol blend for high performance supercapacitors

Y. Ba, W. Pan, S. Pi, Y. Zhao and L. Mi, RSC Adv., 2018, 8, 7072 DOI: 10.1039/C8RA00016F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements